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Hee-Yoon Lee*, Suyoung Ryu, Hongkyu Kang, Young-wook Jun, and Jinwoo Cheon*
Selective Catalytic Activity of Ball-shaped Pd@MCM-48 Nanocatalysts
Chem. Commun., 12, 1325-1327
Selective Catalytic Activity of Ball-shaped Pd@MCM-48 Nanocatalysts
Chem. Commun., 12, 1325-1327
Date: Feb 16, 2006
Remarkable selectivity is achieved in the cleavage of benzyl ethers using ball-shaped palladium nanocatalysts, Pd@MCM-48, in an MCM-48 matrix. The unique nanocatalysts not only feature unprecedented complete hydrogenolysis selectivity of a benzyl ether over hydrogenation of a double bond, but also demonstrate selective cleavage of unsubstituted benzyl ether over substituted benzyl ethers.
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